The required markings for overpacks include: Placards are not required for consolidation bins as the definition and description for a consolidation bin does not include large means of containment. How to Determine Correct UN Number and Proper Other safety marks are shown in Table 2 in this document (below). The alphabetical order has been determined by ignoring all numerical digits and all lower case letters that precede the first capital letter in the shipping name. EDT. This mark is required when shipments meet the excepted quantity exemption. On the periodic table, it has the symbol "Hg" and its atomic number is 80. However, it would be prudent to hire a laboratory with appropriate accreditations. The labels must be displayed on two opposite sides of the outer surface of a small means of containment. Consequently, the compatibility group will be already assigned by the Natural Resources Canada. What are the general requirements for all dangerous goods safety marks? Determine the shipping name: Check if the product name is listed in Schedule 1 or Schedule 3. Mercury is a naturally occurring trace metalloid element and known neurotoxin with atomic symbol Hg, atomic number 80, and atomic weight 200.59. Dangerous goods can present 1 or more of the hazards represented by Class 1 to 9 with some classes split into divisions. If a substance is (gasoline). The material's flash point will be displayed with the unit of measure and followed by "c.c." MERCURY - UMD WebA subsidiary class placard is required to be displayed on a large means of containment for dangerous goods that requires an emergency response assistance plan (ERAP) if they Column 3 Class or Division Contains the class and, in the case of class 1, the division and compatibility group. For example, UN3518 ADSORBED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. has three hazard classes assigned to it in Column 3 of Schedule 1. NOTE: The table below is for guidance purposes only. Note that the, classification (primary and subsidiary hazard classes), whether or not they are shipped under a TDG exemption, Label for the primary hazard class for each dangerous good in the package, Label for the subsidiary hazard class (if any) for each dangerous good in the package, Shipping name and technical name when required in Special Provision 16 in Schedule 2 of the TDG Regulations. 6 CCR 1007-1 Part 17 - 6 CCR 1007-1 Part 17 - RADIATION CONTROL - TRANSPORTATION OF RADIOACTIVE MATERIALS, GA Reg. << For the dangerous goods other than Class 1 DG, a Conveyance Permit (For Dangerous Goods other than Class 1 Dangerous Goods) is required. WebClassification of dangerous goods is broken down into nine classes according to the type of danger materials or items present, click on a class to read more details; 1. Figure 2: Safety marks on a small means of containment such as a package Note 1: The orientation marks for liquids are optional for road transport, but mandatory for air transport. <> See Column 4 in Schedule 1. The type of packages must be indicated by description of the package (for example, 12 drums). Ch. Sodium dithionite or Sodium hydrosulphite, Sodium sulphide, anhydrous or Sodium sulphide, with less than 30% water of crystallization, Dangerous Goods of Class4.2, Packing Group II, not listed above, Fibres or Fabrics, animal or vegetable or synthetic, n.o.s., with oil, Iron oxide, spent or Iron sponge, spent, obtained from hydrocarbon gas purification, Seed cake, with more than 1.5% oil and not more than 11% moisture, Seed cake, with not more than 1.5% oil and not more than 11% moisture. (ii) The hazard class need not be included for the entry Combustible liquid, n.o.s.. Other dangerous goods safety marks that may be required for a shipment of dangerous goods are summarized in Table 2 below. When the shipping name is not a specific name such as a family name, then these shipping names are followed by N.O.S. the date on which the dangerous goods were classified. (gasoline) and the laboratory provided the following test result: Using this data and comparing it to that in Section 2.19, it is determined that this dangerous good needs to be assigned to Packing Group II. International Civil Aviation Organization (ICAO) Technical Instructions for the transport of dangerous goods by air, International Maritime Dangerous Goods (IMDG) Code for the transport of dangerous goods by ship, or. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#b{ogw~0B"ty'{~Oi"v?`"DqXmImPiww#R{;?j}J3]0{ ?>]|YlbE#SsBsz/E":}NCg7ON2P5N}s/w?9LO?zZ^/1BWu~N"r~!P;1FAS*:hzQHo _+3l3E6FAsmH}]fwcxoCcbb,!7cTvt{o&h: foC"uF2c;&4m;vx?=8 ga ` !%6M`Wn-@lM;#={CSaW+r:&|gB7/ndJlXqFxs1}n]N:=jd#]5$b{9NF">OL_7!y;3~*cQlCek4o6 eeGn:9P_mO}W'^q7{X,V{TFi8Qj eg/od{QVg{*Ky3n_0ht vv@9g;OkRz~w}79!^C:[7C .{;T/tUOB9x|]\;Q7W{!~uhM Class 2.1 Dangerous Goods Self-heating solid, corrosive, organic, n.o.s. It exists in several forms: Elemental (metallic) mercury. Scheduled maintenance - Thursday, July 12 at 5:00 PM (4) The packing group in Roman numerals, as designated for the hazardous material in Column (5) of the 172.101 table. For example: UN 1993, Flammable liquids, n.o.s. Code tit. When are dangerous goods safety marks required? ); a person who formulates, blends or otherwise prepares mixtures or solutions of goods (e.g., chemist); or. >> if applicable, the technical name of the dangerous goods, the classification of the dangerous goods, and. p;k0;!N}?s7S&7! Wis. Admin. Has a subsidiary classification of Class 1 (1.1,1.2, 1.3 above the exemption limits), Class 4.3, Class 6.1 (Packing Group I), Class 8 (applies only to UN numbers As per subsection 11.1(1) of the TDG Regulations, the IMDG Code must be consulted for international transport by ship. Identification number - UN Number either within the center of the placard or on an orange panel safety mark (see the table for other safety marks) when required in Sections 4.15.2 of Part 4 in the TDG Regulation. We expect this update to take about an hour. Solutions or Mixtures: When a solution or a mixture consists of one dangerous good mixed with non-dangerous goods (e.g., water) and the properties for the solution are the same as for the pure substance, the shipping name is followed by the word solution or mixture as applicable. CCOHS is not liable for any loss, claim, or demand arising directly or indirectly from any use or reliance upon the information. Mercury Are there any exemptions for placards? as appropriate. Mercury If the dangerous good is an explosive or radioactive material, it must be classified as required by other regulatory authorities. Safety data sheet SECTION 1: Identification of the A substance, mixture, or article that is a marine pollutant and does not meet the classification criteria for inclusion in any other hazard class shall be declared under either UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, n.o.s. WebIn 2007 Mercury Marine began selling its Zeus drive system. Code R. Ch. hbbd``b`$@@YD$;! WebEU mercury 7439-97-6 IOELV 0,02 2009/ 161/EU IE mercury 7439-97-6 OELV 0,02 S.I. Depending on the classification of the dangerous good, one or more of the following safety marks may be required on a small means of containment: See Figure 2 for an example of dangerous goods safety marks on a small means of containment such as a package. Transportation of Dangerous Goods (TDG) - 9 Classes, TDG "Special Case and Special Provision Exemptions. ?O.Q\tF,"V4Iuu8jhb7ew?NI ~eS^lsEU_{\3>e; F]u:MvF7Bz3Jz;O>tzw5qy:!&|]&$fG6F`B@a'\` Eno14}tQ`?K4%1nFh,D_Qg4f>~j $7NH s:o~P;v4fRd%r{6|;>v&K >Z!O~X}u!wv=@~0}$vN=. Transportation of Dangerous Goods (TDG If the dangerous goods are biohazardous substances (Class 6.2), the consignor may use the classification determined by Health Canada or the Canadian Food Inspection Agency. Examples: COTTON WASTE, OILY (UN1364), or REGULATED MEDICAL WASTE, N.O.S. This mark is required when shipments meet the limited quantity exemption, and must be displayed on one side of a means of containment. Make sure the appropriate labels (TDG or Workplace Hazardous Materials Information System (WHMIS) are used in the workplace as required. Please also see the following documents in this series: The consignor is responsible for determining the classification of dangerous goods. Product mixture that consists of multiple dangerous goods: If the shipping name is not a specific name, then the technical name of the most dangerous substance needs to be provided in brackets as required in Special Provision 16 in Schedule 2. Dangerous Goods Information 64-23-14 - 64-23-14 - Transportation of Radioactive Material. When shipping marine pollutants by sea, the proper shipping name shall be be supplemented with the technical name of the marine pollutant. See the example below. Note 4: As the dangerous good is not identified with UN3373, the Category B mark is not required. Determine the other classification elements (i.e., hazard class, packing group, etc.). How do I determine the compatibility group? It is required that proper shipping names be supplemented with the technical or chemical group name. The subsidiary hazard class or division number is not required to be entered when a corresponding subsidiary hazard label is not required. As Marine Pollutants Only: will be unavailable during this time. It is used for dangerous goods that do not have a specific entry by name in Schedule 1. Transport Canada is closely monitoring the COVID-19 situation. Always check the TDG Act and Regulations to ensure compliance. WebClassifying Substances That Are Included in More Than One Class or Packing Group The Primary class is shown first, with the subsidiary classes in brackets. 4 0 obj Admin. Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. For pure chemical substances or well-defined articles, it is easy to choose UN numbers and proper shipping names. ), 3. For an explosive that is an article, such as Cartridges, small arms, the net explosive mass may be expressed in terms of the net mass of either the article or the explosive materials contained in the article. endobj Note: The NA numbers in the 49 CFR are not permitted in Canada. Mercury General What information is needed for classification? Laboratory tests are required for pure substances, solutions, and mixtures. For example: UN1993, FLAMMABLE LIQUID, N.O.S. Generally, the shipping name should be selected in the following hierarchical order: 1. Some manufacturing is in Fond du Lac, while 40-60 HP motors are made in China. How do I determine the shipping name when there are several possible shipping names? Access to this website are classified in the Class 1 hazard class. It can cause headaches, can damage the nervous system of the body. How many placards are required on a large means of containment? You can download all hazard symbols for all hazard classes above by clicking the picture below. Mercury is a highly toxic metal and can cause skin irritation, skin rashes, allergic reactions. Corrosives 9. Products and For example: the mixture is liquid and homogeneous and the ingredients will not separate (e.g., no visible solids or two different phases such as you would observe when oil and water are mixed). Generic risk (e.g., flammable, toxic, etc.). WebClass 1 Explosives; Class 2 Gases; Class 3 Flammable liquids; Class 4 Other Flammable Substances; Class 5 Oxidizing Substances & Organic Peroxides; Class 6 if applicable, the classification method used under Part 2 of the TDG Regulations or under Chapter 2 of the UN Recommendations. Mercury is an element and a metal that is found in air, water, and soil. Wash. Admin. (7) The number and type of packages must be indicated. Note 3: The containers inside the package not required to bear TDG safety marks. Please also see the following documents in this series: The purpose of dangerous goods safety marks is to: Dangerous goods safety marks are required when the good that is being transported: The TDG Regulations (Part 4) specify that all safety marks must be: Responsibilities for dangerous goods safety marks depend on whether the handler of the dangerous goods is the: Before the goods are loaded on the means of transport (i.e., vehicle, truck), the consignor or importer must: Misleading safety marks are dangerous goods safety marks that might be deceptive, ambiguous, or provide false information about the presence or nature of any dangers. Note 2: Package certification safety marks are specified in the standard that the package or container is compliant with. Marine Pollutants: Mercury. WebMercury (Metallic) Quicksilver; Hydrargyrum; Liquid Silver 1.2. Once the material has been tested at a laboratory, the test results are compared to the classification criteria in Part 2. Webmercury and mercury compounds: 0.1 mg/m3 (TWA), skin - ACGIH Threshold Limit Value (TLV): inorganic and metallic mercury, as Hg: 0.025 mg/m3 (TWA) skin, A4 Not What are the requirements for dangerous goods safety marks when displayed on the means of containment. In addition -. The Primary class is shown first, with the subsidiary classes in brackets. Relevant identified uses of the substance or mixture and uses advised against Intended use Application Method 1.3. For hazardous materials transported by sea with a flash point at or below 60 clesius degrees, the IMDG Code requires an indication of the flash point after the proper shipping name. If you are a consultant, you may get yourself listed in CSP business directory (free) or ), 2. A placard is used for a large means of containment whose capacity is more than 450 L. The marks for safety for each TDG class are shown in the OSH Answers document Transportation of Dangerous Goods (TDG) - 9 Classes. EDT. See Section 2.4. The flash point must be indicated for materials with a primary or subsidiary Class 3 hazard. sponsor this page to leave your contact info on this page.. `9yYcQKL U\ >5Iy+&1fXM+DD.> vl=|TOZg]-L8o1016&nY#Xh*4z5tGLUlWi. The class to indicate that the flash point is a closed cup test value (e.g., 27 clesius degrees c.c.). See Section 4.10(5) in the TDG Regulations for circumstances when labels are not required and the "Packaging and Transport of Nuclear Substances Regulations" for specific marking requirements. Subsection 2.2(4) and Parts 9 and 10 of the TDG Regulations authorize you to use the classification from the: Many substances in Schedule 1 are assigned one or more packing groups. Figure 3: Placard requirement and placement for a single dangerous good transported in a highway tank Image from Transport Canada. How does the consignor determine the classification for a dangerous good? :/z6+^OHfamwfe~:[NF/{^f&onaR;`N=EIM&&G* mG6[0b@,d a|};>Swhl_qmlc/ZI/*_:y,B.y'WvPkzZ. or UN 3082 ENVIRONMENTALLY HAZARODUS SUBSTANCE, LIQUID, n.o.s. Class 4 Substances/Products include: Flammable Solids; Substances Liable to Spontaneous Combustion; Substances That on Contact with Water Emit Flammable Gases (Water-reactive Substances), Class 5 Oxidizing Substances, including Organic Peroxides, Class 9 Miscellaneous Products, Substances or Organisms. Mercury Marine Your product may meet the criteria for one or more of the of the following nine TDG hazard classes: If your product meets the criteria for several hazard classes, the primary class must be determined. The Proper Shipping Name shall be supplemented with "MOLTEN"; Stabilized substances: Figure 3: Labels on cylinders. From the surface of Mercury, the Sun would appear more than three times as large as it does when viewed from Earth, and the sunlight would be as much as seven times brighter. NOTE: The size of the Inhalation hazard letters vary for different types of means of containment. They will be used to label dangerous goods. These criteria are outlined in the TDG Regulations. Which words shall be added depend on the hazard, composition, state of the dangerous goods and the mode of transport. For most of dangerous goods, the primary class and subsidary class can be found in Dangerous Goods List. (6) For transportation by aircraft, the total net mass per package, must be shown unless a gross mass is indicated in Columns (9A) or (9B) of the 172.101 table in which case the total gross mass per package must be shown; or, for Class 7 materials, the quantity of radioactive material must be shown by activity. a person capable of understanding the nature of the dangerous good (e.g., manufacturer's professional employees such as a chemical engineer, chemist, scientist, etc. Mercury The main product line is outboard motors. Note: The information below is provided as guidance only. Code 3701:1-50-23 - 3701:1-50-23 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. Safety Data Sheet Mercury (Metallic) - WMSolutions.com }qI;<>q2=4s; y5J Flammable solids 5. You can However, if the product's name is not listed in Schedule 1 or 3, then the product must be tested at a laboratory. Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. UN 3506: Mercury contained in manufactured articles - Substance What is its predominant hazard substance and primary hazard? Note: The information below is provided as guidance only. Mercury's surface temperatures are Dangerous goods safety marks are the first line of communication about the hazard(s) of the dangerous good. Is "Waste", "Molten", "Stabilized", "Flash point", "Marine Pollutant" applicable. The technical name shall be a recognized chemical or biological name, or other name currently used in scientific journals and handbooks. ), 4. The Proper Shipping Name must be preceded by the word "WASTE"; Solid transported in a molten state: Regulatory information United States of America Inventory Component CAS-No TSCA TSCA Inventory notification - Active/Inactive TSCA - EPA Regulatory Flags Mercury Wastes: Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. The following packing group always takes precedence irrespective of hazards: The following hazard class always takes precedence irrespective of packing groups: If above two rules do not apply, please refer to the following hazard precedence table to choose primary hazard. Danger placard (instead of the individual hazard class placards) may be displayed when only the following dangerous goods are present in the shipment are classified in: Class 2 gases shipment in combination of two or more cylinders that have a combined capacity exceeding 450 L such that: The combination of cylinders may be placarded as one large means of containment. Shipping Limited Quantities or Excepted Quantities from If you are a consultant, you may get yourself listed in CSP business directory (free) or The subsidiary class is the other class that further identifies the hazards of the dangerous goods. S.C. Code Regs. [1] Are the classifications for other modes or international shipments the same? There are 4 types of entries consisting of UN numbers and proper shipping names in the Dangerous Goods List. ), MARINE POLLUTANT. Large means of containment: These words must be displayed on two opposite sides of the large means of containment in addition to any other safety marks that are required under the TDG Regulations. The smallest planet in our solar system and nearest to the Sun, Mercury is only slightly larger than Earth's Moon. "6%X3$dl@7H,d100K@ ^/ If the dangerous goods are radioactive, the consignor must use the classification determined by the Canadian Nuclear Safety Commission. Select country for which that subsidiary belongs to. subsidiary class Nitrites and their mixtures. Figure 1: Label and placard (Image from Transport Canada). (iii) the primary class, which may be shown as a number only or under the heading Class or Classe or following the word Class or Classe. 1. Flammable solid, corrosive, organic, n.o.s. A proof of classification is a document that the consignor must provide, upon request, to the federal Minister of Transport. WebClass 3 material except PG I materials with a subsidiary hazard and UN1204, UN2059, UN3064, UN3256, UN3269 (unless authorized under SP A163), UN3357, UN3379, and UN3474 Division 4.1 PG II and PG III materials except UN2304, UN2448, UN2555, UN2556, UN2557, UN2907, UN3176, UN3221 through UN3240, UN3319 and UN3344 For example: UN3086, TOXIC SOLID, OXIDIZING, N.O.S. %PDF-1.5 % entries are assigned with special provisions 274 or 318 (see column 6 in the example below). However, if the dangerous goods are explosive, the consignor must use the classification determined by the Natural Resources Canada. Solids containing flammable liquid, n.o.s. See Section 2.5. Code 5-481-3120 - 12VAC5-481-3120 - Advance notification of transport of nuclear waste. If two or more dangerous goods have different UN numbers but are identified by the same placard or placards, the placard is required to be displayed only once on each side and on each end of a large means of containment regardless of how many products in the large means of containment have that class (primary or subsidiary) [See Section 4.15 in the TDG Regulations]. Code 5-3-25.4 - 410 IAC 5-3-25.4 - Advance notice of transport of nuclear waste, Kan. Admin. Inhalation Hazard words on two opposite sides of the containment for dangerous goods: as listed in Special provision 23 in Schedule 2 of the TDG Regulations, classified in Class 6.1, Toxic substances because the dangerous good meets the inhalation toxicity criteria and Class 2.3, Toxic Gases, Elevated temperature sign (if applicable), Container certification or compliance marks as required by the standard that the container is compliant with, a placard and UN number may be displayed on two opposite sides of the intermediate bulk container, or, a label for each primary and subsidiary class as well as a UN number and a shipping name may be displayed on two opposite sides of the intermediate bulk container. Mercury Column 5 Packing Group Contains the packing group number (i.e. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Substances (including substances and mixtures), and articles are assigned to one of the following 9 classes according to the most predominant hazards they pose in transport. Specific chemical name (e.g., acetone, sulfuric acid, etc. How to Ship Hazmat with No Packing Group | Lion Technology Basic Information about Mercury Class1.1, 1.2, 1.3 or 1.5 explosives that are: not subject to Special Provision 85 or 86 and the quantity is less than or equal to 10 kg, or, subject to Special Provision SP 85 or 86 and the quantity is less than or equal to 1000 articles (note: this is number of articles, not mass), Class 1.4 (except Class 1.4S) is 1000 kg or less, Class 6.1 and are not required to comply with Special Provision 23, Class 6.1 but are not an inhalation hazard and are not listed in Special Provision 23. capacity of each cylinder is greater than 225 L, are interconnected through a piping arrangement, and, are permanently mounted on a structural frame for transport, Class 6.1 for exposure to other routes (not an inhalation hazard)and are not listed in Special Provision 23, Class 6.1, Toxic Substances due to inhalation toxicity, Are dangerous goods subject to Special Provision 23. They are substances that are identified as Marine pollutants in the IMDG Code Index or substances that satisfy the GHS classification criteria for Hazardous to Aquatic Environment Acute 1, Chronic 1, or Chronic 2. Trade name is not accepted. Mercury Factsheet | National Biomonitoring Program | CDC Dangerous Goods Classes and Symbols Yes. Admin. Appendix E: Schedule 2 - List of Dangerous Goods WebIf a type 3 vessel carrying Class 1 DG on board would staying over-night at the WDGA, notification in writing to the Dangerous Goods Unit of the Marine Department will need to be given. Use the shipping name and its corresponding data (UN number, class, packing group/category) in Schedule 1 to assign the classification to the dangerous good. Class 6.1 (5.1) Packing Group I. WebIdentification Product Name Mercury (Certified ACS) Cat No. The type of packaging and destination marks may be entered in any appropriate manner before or after the basic description. If you like this article, please share it. 172.202 Description of hazardous material on shipping papers. Abbreviations may be used to express units of measurement and types of packagings. (iii) For domestic shipments, primary and subsidiary hazard class or division names may be entered following the numerical hazard class or division, or following the basic description. What safety marks are required on a small means of containment (capacity 450L or less)? This communication is accomplished by the: Note that the difference between labels and placards is their size.
